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James G. Donohue began their career as a Substitute Teacher at Charles County Public Schools in 2004 before transitioning to the US Army in 2008, where they served as a Field Artillery Officer until 2015. James G. then joined Goodwill Central Texas in 2015 as a Logistics Manager and progressed through various roles, ultimately becoming the Senior Director of Supply Chain in 2021. Throughout their tenure at Goodwill, James led operations, managed staff, secured contracts, and streamlined processes to support the organization's waste diversion and revenue generation goals.

James G. Donohue obtained a Bachelor of Arts in English Literature from the University of Richmond in 2008. James G. later pursued a Project Management Fundamentals Certificate from Syracuse University in the School of Information Studies in 2016.