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Vic Alexander started their work experience in 1994 at St Helen's, Northwood, where they worked as a PE teacher for both the Prep and Senior School until 1997. They then moved on to Wimbledon High School, where they worked as a PE teacher and Sports Club Administrator from 1997 to 2001. In the same year, Vic also started working at St Catherine's School, Bramley, holding multiple roles such as Designated Safeguarding Lead, PE Teacher, Lacrosse Coach, and Director of Sport. Vic continued their work at St Catherine's School and became the Head of 6th form boarding and PE Teacher in 2016.

Vic Alexander attended Queen Anne's School in Caversham from 1983 to 1990. However, it is not specified whether they obtained a degree or pursued any specific field of study during this time. Subsequently, from 1990 to 1994, they attended the University of Brighton, where they obtained a Bachelor of Education (BEd) degree in Physical Education and Maths.