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Sun Jigui has extensive work experience in the mining industry, starting with their role as a Geologist at The Eighth Geological Exploration Brigade of Hebei Province from 1984-1985. SUN then worked at The Gold Headquarters of the Chinese Armed Police as Head of Geology Division and Senior Exploration Geologist from 1988-2002. Sun Jigui continued their career as Project Manager and Senior Geologist at Yunnan Jinchangjiang Mining Ltd, a joint venture of Silvercorp Metals, from 2002-2004. SUN then served as General Manager at Sichuan Huaxi Exploration & Mining Ltd, another joint venture of New Pacific Metals Corp, from 2004-2008. Following that, Sun Jigui worked as General Manager at Guangdong Found Mining Ltd, a joint venture of Silvercorp Metals, from 2008-2010. Currently, they are employed as the Chief Manager of the Investment Centre at Silvercorp Metals Inc, where they have been working since 2011.

Sun Jigui holds a Master of Science degree in Geomachanics from the Graduate School of the Chinese Geoscience Academy. SUN obtained this degree from 1985 to 1988. Prior to that, they completed their Bachelor's degree in Geological and Earth Sciences/Geosciences from Changchun Geology College, which they attended from 1980 to 1984.