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June Donnan has a diverse work experience in the education field. June started their career in 1996 as a Deputy Headteacher at King's Group, where they worked until June 2019. During their time there, they also served as the Head Teacher and a Youth Mental Health First Aid England accredited trainer. In 2016, they joined COBIS - Council of British International Schools as a CPML and CPAH facilitator. In 2018, they briefly worked as an Acting Head teacher at King's Infant School, Chamartín.

June Donnan has a Bachelor of Arts degree in Hons from the University of Ulster. June further pursued their education and earned a Masters in Education from The Open University in the years 1998 to 2001. To enhance their leadership skills, June completed a Masters in Leadership and Management from The Open University between 2004 and 2006. Finally, in 2008 to 2009, they attended the National College for School Leadership to obtain a National Professional Qualification for Headship (NPQH) with a focus on leadership.