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De Daltorio began their work experience in 1996 as an Art Teacher at St. Alphonsus School, where they remained until 2008. In 2009, they joined the Charleston Animal Society as the Chief Education Officer. Their most recent role, starting in 2023, is as the Senior Advisor for the Board of Directors at the Association of Professional Humane Educators.

De Daltorio has a Bachelor of Arts degree in Elementary Education from Indiana University of Pennsylvania. Additionally, De Daltorio has pursued Art Education at Carlow University. However, no specific start or end years were provided for either educational experience.