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Sergio Salvio has extensive work experience in various financial and strategic roles. Sergio is currently serving as the Chief Financial Officer and Chief Strategy & Sustainability Officer at ANAS SpA. In addition, they are the Chairman of Mercitalia Rail. Sergio previously held positions at FS Sistemi Urbani, where they served as the CFO - Dirigente Preposto, as well as the Chief Financial Officer & Chief Information Officer. Sergio has also served as a Board Member at Italferr S.p.A., Quadrante Europa Terminale Gate, and Italcertifer S.p.A. Furthermore, they held leadership positions at Rete Ferroviaria Italiana and TFB Tunnel Ferroviario del Brennero. Before that, they worked as the Head of Budget and Control of Business Unit at F.S S.p.A. - Ferrovie dello Stato - Rome, and as the Head of Business Strategies in the Strategies and Planning Area at TAV SpA.

Sergio Salvio has a Bachelor's degree in economics from Università degli Studi di Napoli Federico II, which they completed from 1980 to 1986. In 1986, they also obtained a Master in Business Administration from IFAP-IRI. In 1993, Sergio attended the Visitors International Programme to study economics. Most recently, in 2021, they completed a program in Advanced International Corporate Finance at INSEAD. There is no information provided regarding the duration or field of study at De La Salle Naples.