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Alessandro Napoli has over 20 years of work experience, with roles in various organizations. Alessandro started their career as a Researcher at IsICult in 2000. Alessandro then worked at the World Food Programme from 2002 to 2017, where they held positions such as HR/Training Officer, Change Management Technical Coordinator for Learning, and Training Officer. From 2012 to 2015, Alessandro also worked as a Training Officer at the Food and Agriculture Organization of the United Nations. Alessandro then joined UNHCR in 2015 as a Senior Learning Solutions Officer and later moved to the World Food Programme as the Head Learning Technology and Language Learning. Alessandro also briefly worked as a Senior Human Resources Officer at the World Food Programme in 2023. Alessandro has extensive experience in talent management, learning solutions, and training.

Alessandro Napoli earned a Laurea in Scienze della Comunicazione (110/110 cum laude) from Sapienza Università di Roma from 1992 to 1998. Alessandro'sfield of study included Mass Media, Communication, Sociology, and Semiotics. In 2018, they also obtained a certification in "Coexistence in Medieval Spain: Jews, Christians, and Muslims" from the University of Colorado System on Coursera.