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Xiaoling Li has a long and varied work experience. Xiaoling began their career in 1991 as a Post Doctoral Research Fellow at Ciba-Geigy. In 1993, they started working at the University of the Pacific, where they held roles such as Professor of Pharmaceutics, Associate Dean, Chair of the Department of Pharmaceutics and Medicinal Chemistry, and Director of Pharmaceutical and Chemical Sciences Graduate Program from 2000 to 2006. Xiaoling also served as an Assistant and Associate Professor. In 2006, they co-founded Formurex, where they served as Co-founder and CSO. In 2015, they co-founded Triastek, Inc. and served as Co-founder.

Xiaoling Li attended Shanghai First Medical College from 1978 to 1982, where they obtained their Bachelor of Science in Pharmacy. Xiaoling then attended Shanghai Medical University from 1982 to 1985, where they obtained their Master of Science in Nuclear Pharmacy. From 1987 to 1991, they attended the University of Utah and obtained their Doctor of Philosophy in Pharmaceutics. In 2013, they attended Harvard University and completed a program in Management and Leadership in Education.