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Mercedes Alexander began their work experience in 2006 as a Grants & Contracts Coordinator at SPARKS. In October of that year, they joined Samueli Institute as a Grants & Contracts Manager, a position they held until August 2015. In August 2015, Mercedes started working at Patient-Centered Outcomes Research Institute (PCORI) as a Contract Administrator, and later became a Senior Contract Administrator in January 2018.

Mercedes Alexander attended James Madison University from 2000 to 2005, where they obtained two bachelor's degrees. Mercedes graduated with a Bachelor of Science in Kinesiology and Exercise Science and a Bachelor of Business Administration in Marketing.