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Caroline Sister has a diverse work experience. Caroline currently serves as the Chief of Staff, Operations Manager, and Personal Assistant to the CEO at MurphyCobb & Associates Ltd - Global Production Investment Experts since June 2023, December 2022, and May 2022 respectively. Before joining MurphyCobb & Associates, they worked as a Juíza Leiga at Tribunal de Justiça do Estado do Rio de Janeiro from June 2019 to October 2022. Prior to that, they were an Advogado at an undisclosed company from August 2006 to June 2019. Caroline also worked as an Advogada de Direito Societário e Contratos at Eskenazi Pernidji Advogados from January 2005 to August 2006, and as an Estagiário em Direito Empresarial at Eskenadji Pernidji Advogados from July 2001 to December 2004.

Caroline Sister completed their Master's degree in Law from Universidade do Porto from 2020 to 2022. Prior to that, from 2019 to 2020, they pursued post-graduate studies in Criminal Law and Criminal Procedure from Universidade Candido Mendes. In 2000, they completed their undergraduate degree in Law from the same institution. Additionally, Caroline obtained a certificate of participation in the "Curso de Tratamento de Dados Pessoais: Atualidade e Tendências" from AEFDUCP (Associação de Estudantes da Faculdade de Direito da Universidade Católica Portuguesa) in June 2021. Caroline also holds a Certificate of Proficiency in English from The University of Michigan, which they obtained in November 1998.