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James Klempster's work experience begins in 2004 at NW Brown Group Ltd, where they worked as an Assistant Fund Manager from September 2004 to November 2005. In 2005, they joined Avebury AM as a Portfolio Manager until 2007. From April 2007 to February 2021, they served as the Head of Investment Management at Momentum Global Investment Management. Currently, they are the Deputy Head of Multi Asset at Liontrust Asset Management PLC, a position they have held since February 2021.

James Klempster attended the University of Oxford from 2000 to 2004, where they obtained a Master of Arts (M.A.) degree in Jurisprudence. Prior to that, they attended the Samuel Whitbread Community College, but no information is provided regarding the duration of their studies or the degree and field of study pursued.